Ultrafast Laser-Induced Crystallization of Lead Germanate Glass

نویسندگان

چکیده

Laser-induced space-selective crystallization of glass enabling the growth continuous crystal-in-glass architectures consisting non-centrosymmetric phases with functional properties is promising, including single-crystal waveguides for development integrated optical circuits. In this study, femtosecond laser direct writing crystalline lines inside lead germanate composition close to Pb5Ge3O11 has been demonstrated. The by .moving focused beam required preliminary a seed crystal fixed beam. Confocal Raman spectroscopy revealed precipitation ferroelectric Pb5Ge3O11, which, under certain exposure conditions, could be accompanied metastable phase. Depending on parameters, either bilateral providing split, horseshoe-shaped morphology cross-section, or centered resulting in elongated, elliptical cross-section shape occurred. obtained results are interest fabrication Pb5Ge3O11-based waveguides.

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ژورنال

عنوان ژورنال: Crystals

سال: 2021

ISSN: ['2073-4352']

DOI: https://doi.org/10.3390/cryst11020193